Prediction of Corrosion Inhibition Efficiency of Acalypha godseffiana leaves Extracts
Keywords:
Inhibition efficiency, weight loss measurement, Corrosion, Plant extracts, Mild steel, Statistical analysis.Abstract
As a follow up on our previous studies (Mathematical Modelling of Corrosion Inhibition Efficiency of Acalypha Wilkesiana Leaves) Acalypha godseffiana leaves were collected at Adeyemi College of Education, Ondo. Cleaned leaves were subjected to sun-dry and air-dry processes. Sun-dried and air-dried leaves were powdered, sieved and stored in desiccators at room temperature. A known mass of the powdered leaves was soaked in ethanol in different containers for 72 hours to obtain inhibitor extracts. Extracts were used as inhibitor for mild steel of known composition. Weight loss, inhibition efficiency (IE) and corrosion rate were studied using standard methods. Models that relate concentration of inhibitor, temperature to IE were proposed, established and evaluated using statistical methods. . The inhibition efficiency increases with increasing extracts concentration to 88.43 % and 88.37 % at 333K of 1.0 g/l of extracts for the air and sun-dried extracts, respectively. CD, MSC, AIC and SC were in the range of 0.8794 to 0.9790, 2.1 to 4.1, 67.3 to 104.8 and 73.1 to 101.8 for both air and sun dried extracts.
The table revealed that the best models for sun and air dried extracts were linear with interaction with MSC (3.6 and 4.1), AIC (73.1 and 64.3) and SC (76.1 and 67.3), respectively. The worst models for sun and air dried extracts were log-linear without interactions and non- linear without interaction with MSC (2.1 and 2.9) , AIC (101.8 and 86.6) , SC (104.8 and 89.6), respectively. The cost analysis revealed that it is economical to utilise plant leaves extract. It was concluded that these two extracts of the present study can serve as effective green corrosion inhibitors for mild steel in acidic media and further investigations to assess the corrosion morphology and to isolate and confirm the active phytochemicals responsible for the inhibition of mild steel corrosion in acidic media are required.
References
Anees, A. K,., Ahmed, N. A. and Nagham, A. A. (2018). Xanthium strumarium leaves extracts as a friendly corrosion inhibitor of low carbon steel in hydrochloric acid: Kinetics and mathematical studies. South African Journal of Chemical Engineering 25, 13 - 21
Finšgar, M and Jackson, J (2014) Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: A review / Corrosion Science 86 (2014) 17–41
Karthik, G and Sundaravadivelu, M. (2016). Studies on the inhibition of mild steel corrosion in hydrochloric acid solution by atenolol drug. Egyptian Journal of Petroleum (2016) 25, 183–191
Obi-Egbedi, N.O. Obot, I.B and Umoren, S.A (2012). Spondias mombin L. as a green corrosion inhibitor for aluminium in sulphuric acid: Correlation between inhibitive effect and electronic properties of extracts major constituents using density functional theory. Arabian Journal of Chemistry . 5, 361–373.
Al-Otaibi,M.S. ,A.M. Al-Mayouf, M. Khan, A.A. Mousa, S.A. Al-Mazroa and H.Z. Alkhathlan (2014). Corrosion inhibitory action of some plant extracts on the corrosion of mild steel in acidic media. Arabian Journal of Chemistry 7, 340–346.
Yaro, A.S., Khadom, A.A., and Wael, R.K., (2014). Garlic powder as a safe environment green corrosion inhibitor for mild steel in acidic media; adsorption and quantum chemical studies. J. Chin. Chem. Soc. 61, 615 - 623.
Yaro, A.S., Khadom, A.A., and Wael, R.K., 2013. Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid. Alexandria Eng. J. 52, 129 – 135
Khadom, A.A., and Abdul-Hadi, A.A., (2014). Kinetic and mathematical approaches to the corrosion of mild steel in nitric acid. Reac. Kinet. Mech. Cat. 112, 15 - 26.
Sanjay, K.S., Peter, A., and Obot, I. B., (2015). Potential of Azadirachta indica as a green corrosion inhibitor against mild steel, aluminum, and tin: a review. J. Anal. Sci. Technol. 6, 26 - 33.
Alaneme, K.K., Daramola, Y.S., Olusegun, S.J., Afolabi, A.S., (2015). Corrosion inhibition and adsorption characteristics of rice husk extracts on mild steel immersed in 1M H2SO4 and HCl solutions. Int. J. Electrochem. Sci. 10, 3553 - 3567
Khadom, A.A., Hassan, A.F., and Abod, B.M., (2015). Evaluation of environmentally friendly inhibitor for galvanic corrosion of steelecopper couple in petroleum waste water. Process Saf. Environ. Prot. 98, 93 – 101
Ghulamullah, K., Kazi M. S., Newaz, W. J., Basirun, H. B., Mohd, A., F. Lafta, F., G. and Mustafa, K., (2015). Application of natural product extracts as green corrosion inhibitors for metals and alloys in acid pickling processes e a review. Int. J. Electrochem. Sci. 10, 6120 – 6134
Hassan, K.H., Khadom, A.A., and Kurshed, N.H., (2016). Citrus aurantium leaves extracts as a sustainable corrosion inhibitor of mild steel in sulfuric acid. South Afr. J. Chem. Eng. 22, 1 – 5
Fouda, A.S., Megahed, H.E., Fouad, N., Elbahrawi, N.M., (2016). Corrosion inhibition of carbon steel in 1 M hydrochloric acid solution by aqueous extract of Thevetia peruviana. J. Bio Tribo Corros. 2, 16 - 22.
Nathiya, R.S., and Vairamuthu, R., (2017). Evaluation of Dryopteris cochleata leaf extracts as green inhibitor for corrosion of aluminium in 1 M H2SO4. Egypt. J. Petroleum 26, 313 – 323
APHA, Standard Method for the Examination of Water and Wastewater, 21st edn, America Water Works Association and Water Pollution Control Federation, Washington DC. 2012
van Loosdrecht, M.C.M., Nielsen, P.H.,Lopez-Vazquez, C.M., Brdjanovic, D., (2016). Experimental Methods in Wastewater Treatment. 1st Edition, International Water Publishing Alliance House, London
Oke, I. A. ; Ismail, A. ; Lukman, S. ; S. O. Ojo, O. O. Adeosun, and M. O. Nwude (2016). Economics and Statistical Evaluations of Using Microsoft Excel Solver in Pipe Network Analysis. J. Pipeline Syst. Eng. 7(4): 06016002-1- 9
Oke, I. A.; Lukman, S. and Ismail, A(2017). Development And Performance Evaluation Of A New Numerical Model For Groundwater Recharge Estimation. Nigeria Journal of Engineering , 23(2), 56 -65
Barati, R (2013) Application of Excel Solver for Parameter Estimation of the Nonlinear Muskingum Models. KSCE Journal of Civil Engineering, 17(5):1139-1148
Tay, K. G; Kek, S. L. and Rosmila A. K. (2014). Solving Non-Linear Systems by Newton’s Method Using Spreadsheet Excel.
Hui, Z., Xue, Z., Luobin W., Kai, W. and Wendong, W. (2018) Development of a software tool for teaching real‐time state simulation of water distribution networks, Computer Applications in Engineering Education, 26 (3), 577-588.
Akaike, H. An information criterion (AIC), Math. Sci. Vol. 14,1976 , pp 1-5.
Umoren, S.A., U.M. Eduok, M.M. Solomon, and A.P. Udoh (2016). Corrosion inhibition by leaves and stem extracts of Sida acuta for mild steel in 1 M H2SO4 solutions investigated by chemical and spectroscopic techniques. Arabian Journal of Chemistry 9, S209 – S224
Downloads
Published
How to Cite
Issue
Section
License
Authors who submit papers with this journal agree to the following terms.