Studies on the Recovery of Cu (II) and U (VI) on Highly Adsorptive Modified Magnetic Amine Resins from Dolostone Leachate Solution
Keywords:
Magnetic resin, Uranium, Dolostone, Waste.Abstract
Magnetic chelating resin containing amine moiety was obtained by polymerization of chloromethyl styrene with both 5 % and 10% divinylbenzene as a crosslinking agent in the presence of Fe3O4 as magnetite particles, the yield was treated with malononitrile followed by reaction with hydrazine hydrate in the presence of absolute ethanol to get hydrazenyl amine polymer. The obtained resins were investigated by FT-IR, elemental analysis and SEM. The use of magnetite particles was used for increasing the surface of chelating active sites and easy collection from solution. The obtained resins were evaluated toward the uptake of Cu (II) and U (VI) from their aqueous synthetic solutions followed by application on acid leachate of dolostone ore materials from southwestern Sinai. Contact time, pH and initial concentration of the metal ions were investigated as factors affecting the uptake behavior. The modified resins display higher uptake capacity compared to the metal oxide-free resin also high regenerated efficiency.
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